Bis(μ-bis{[4-(2-pyridyl)pyrimidin-2-yl]sulfanyl}methane)disilver(I) bis(perchlorate)

Bis(μ-bis{[4-(2-pyridyl)pyrimidin-2-yl]sulfanyl}methane)disilver(I) bis(perchlorate)

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In the macrocyclic centrosymmetric dinuclear complex, [Ag2(C19H14N6S2)2](ClO4)2, the AgI atom, bis{[4-(2-pyridyl)pyrimidin-2-yl]sulfanyl}methane (2-bppt) ligand and perchlorate anion each lie on a twofold rotation axis.The Power Supply Board 2-bppt ligand chelates two four-coordinated AgI atoms through its two bipyridine-like arms.The O atoms of the perchlorate anion are disordered each Ric Rac over two positions of equal occupancy.Adjacent complex molecules are linked by π–π interactions between the pyridine and pyrimidine rings [centroid–centroid distance = 3.

663 (8) Å].